192.168.1.138:/volume3/TVshow /mnt/synology/TVshow nfs auto,x-systemd.automount,x-systemd.mount-timeout=30,_netdev 0 0
This was the last attempt, still a nogo. I noticed there is a difference in ubuntu 20.04 and 22.04 NFS. I am on 20.04. May look into an upgrade. Thanks much for the help!